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dc.contributor.author Arslan, H
dc.contributor.author VanDerveer, D
dc.contributor.author Ozdemir, I
dc.contributor.author Gurbuz, N
dc.contributor.author Gok, Y
dc.contributor.author Cetinkaya, B
dc.date.accessioned 2021-04-01T08:25:34Z
dc.date.available 2021-04-01T08:25:34Z
dc.date.issued 2009
dc.identifier.uri http://hdl.handle.net/11616/29453
dc.description.abstract The asymmetric unit of the title compound, (C13H15N2S2)-[RuCl3(C10H14)], contains a 1,3-(2-thienylmethyl)-4,5-dihydroimidazolium cation and a trichlorido(eta(6)-p-cymene)ruthenate(II) anion. The thiophene rings of the cation are disordered by an 180 degrees rotation about the thiophene-CH2 bonds with occupancies of 0.847 (5)/0.153 (5) and 0.700 (5)/0.300 (5), respectively. The Ru atom exhibits a distorted octahedral coordination with the benzene ring of the p-cymene ligand formally occupying three sites and three Cl atoms occupying the other three sites. The short C-N bond lengths in the imidazoline ring indicate partial electron delocalization within the N-C-N fragment. Cation and anions are connected through five intermolecular C-H center dot center dot center dot Cl hydrogen bonds and one C-H center dot center dot center dot pi hydrogen bond, forming a three-dimensional hydrogen-bonded network.
dc.title 1,3-Bis(2-thienylmethyl)-4,5-dihydroimidazolium
dc.title trichlorido(eta(6)-p-cymene) ruthenate(II)

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