Synthesis of bridged palladium-PEPPSI complexes and catalytic studies in

dc.contributor.author	Imik, F
dc.contributor.author	Yasar, S
dc.contributor.author	Ozdemir, I
dc.date.accessioned	2022-10-05T12:55:12Z
dc.date.available	2022-10-05T12:55:12Z
dc.date.issued	2019
dc.identifier.uri	http://hdl.handle.net/11616/62172
dc.description.abstract	A series of dimetallic NHC-Pd-PEPPSI complexes with phenylene-bridged N-heterocyclic carbenes (NHC) were synthesized and fully characterized by H-1 NMR, C-13 NMR, HRMS, FTIR, and elemental analysis. The N tags were 2,3,4,5,6-pentamethylbenzyl, 3,5-dimethylbenzyl, 4-tert-butylbenzyl and 3-methoxybenzyl groups. The catalytic properties of the complexes were investigated in the Suzuki-Miyaura reactions of aryl bromides with arylboronic acid and in the Heck coupling reactions of aryl bromide with styrene and in the Sonogashira reactions of aryl bromides with phenylacetylene. Generally, dimetallic complexes exhibit good catalytic activities in the Suzuki-Miyaura, Heck, and Sonogashira coupling reactions.
dc.description.abstract	C1 [Imik, Fatma; Yasar, Sedat; Ozdemir, Ismail] Inonu Univ, Dept Chem, Catalysis Res & Appl Ctr, TR-44280 Malatya, Turkey.
dc.source	INORGANICA CHIMICA ACTA
dc.title	Synthesis of bridged palladium-PEPPSI complexes and catalytic studies in
dc.title	C-C cross-coupling reactions

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