| dc.contributor.author | Çetinkaya, B. | |
| dc.contributor.author | Özdemir, I. | |
| dc.contributor.author | Bruneau, C. | |
| dc.contributor.author | Dixneuf, P.H. | |
| dc.date.accessioned | 2022-10-06T09:37:20Z | |
| dc.date.available | 2022-10-06T09:37:20Z | |
| dc.date.issued | 1997 | |
| dc.identifier.issn | 13811169 (ISSN) | |
| dc.identifier.uri | http://hdl.handle.net/11616/62976 | |
| dc.description.abstract | A variety of neutral arene-ruthenium-carbenes of type (arene)RuCl2(=C(NR)CH2CH2NR) have been used for the catalytic transformation of (Z)-3-methylpent-2-en-4-yn-1-ol into 2,3-dimethylfuran. The catalytic reaction takes place at 80°C with mononuclear complexes III-V to afford the furan in ~90% yield. The binuclear catalysts VIa and VIIa having a linked bis-carbene bridge operate at room temperature to initiate an exothermic reaction offering 90-97% of furan. | |
| dc.source | Journal of Molecular Catalysis A: Chemical | |
| dc.title | Ruthenium-carbene catalysts for the synthesis of 2,3-dimethylfuran |
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