| dc.contributor.author |
Arslan, H |
|
| dc.contributor.author |
VanDerveer, D |
|
| dc.contributor.author |
Demir, S |
|
| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Cetinkaya, B |
|
| dc.date.accessioned |
2022-10-19T09:38:57Z |
|
| dc.date.available |
2022-10-19T09:38:57Z |
|
| dc.date.issued |
2009 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/82409 |
|
| dc.description.abstract |
A novel N-heterocyclic carbene derivative, C(28)H(33)N(2)O(3)(+)center dot-Br(-)center dot H(2)O, was synthesized and characterized by elemental analysis, (1)H and (13)C-NMR and IR spectroscopy and a single-crystal X- ray diffraction study. Ions of the title compound are linked by pi center dot center dot center dot pi stacking interactions (face-face separation 3.441 angstrom) and C-H center dot center dot center dot Br and O-H center dot center dot center dot Br interactions. Intra- and intermolecular C-H center dot center dot center dot O interactions are also present. The C-N bond lengths for the compound [1.329 (3), 1.325 (3), 1.389 (3) and 1.391 (3) angstrom] are all shorter than the average single C-N bond length of 1.48 angstrom, thus showing varying degrees of double-bond character. |
|
| dc.description.abstract |
C1 [Arslan, Hakan] Fayetteville State Univ, Dept Nat Sci, Fayetteville, NC 28301 USA. |
|
| dc.description.abstract |
[Arslan, Hakan] Mersin Univ, Fac Pharm, Dept Chem, TR-33169 Mersin, Turkey. |
|
| dc.description.abstract |
[VanDerveer, Don] Clemson Univ, Dept Chem, Clemson, SC 29634 USA. |
|
| dc.description.abstract |
[Demir, Serpil; Ozdemir, Ismail] Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44280 Malatya, Turkey. |
|
| dc.description.abstract |
[Cetinkaya, Bekir] Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey. |
|
| dc.source |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
|
| dc.title |
1-(4-tert-Butylbenzyl)-3-(3,4,5-trimethoxybenzyl)benzimidazolium bromide |
|
| dc.title |
monohydrate |
|