| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Gurbuz, N |
|
| dc.contributor.author |
Gok, Y |
|
| dc.contributor.author |
Cetinkaya, B |
|
| dc.date.accessioned |
2022-10-19T11:01:30Z |
|
| dc.date.available |
2022-10-19T11:01:30Z |
|
| dc.date.issued |
2008 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/82543 |
|
| dc.description.abstract |
Novel 1,3-dialkylimidazolidinium, 1,3-dialkyl-3,4,5,6-tetrahydropyrimidinium, and 1,3-dialkyl-1H-4,5,6,7-tetrahydrodiazepinium hexafluorophosphates (la-c, 2a-c) as N-heterocyclic carbene precursors have been synthesized and characterized. The incorporation of saturated N-heterocyclic carbenes into palladium precatalysts gives high-catalyst activity in the Heck coupling of aryl bromide substrates in aqueous media. The complexes were generated in the presence of Pd(OAC)(2) by in situ deprotonation of 1,3-dialkylazolinium salts 1, 2. (C) 2008 Wiley Periodicals, Inc. |
|
| dc.description.abstract |
C1 [Oezdemir, Ismail; Guerbuez, Nevin; Goek, Yetkin] Inonu Univ, Dept Chem, Fac Sci & Art, TR-44280 Malatya, Turkey. |
|
| dc.description.abstract |
[Cetinkaya, Bekir] Ege Univ, Dept Chem, Fac Sci, TR-35100 Bornova, Turkey. |
|
| dc.source |
HETEROATOM CHEMISTRY |
|
| dc.title |
N-functionalized azolin-2-ylidene-palladium-catalyzed Heck reaction |
|