| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Demir, S |
|
| dc.contributor.author |
Sahin, O |
|
| dc.contributor.author |
Buyukgungor, O |
|
| dc.contributor.author |
Cetinkaya, B |
|
| dc.date.accessioned |
2022-10-19T11:01:37Z |
|
| dc.date.available |
2022-10-19T11:01:37Z |
|
| dc.date.issued |
2008 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/82651 |
|
| dc.description.abstract |
Reaction of ortho-xylylbis(N-2,4,6-trimethylbenzylimidazolinium);xylylbis(N-butylimidazolinium) and para-xylylbis(N-2,4,6-trimethylbenzylimidazolinium); xylylbis(N-butylimidazolinium) salts with KOBut and [RhCl(COD)](2) yields ortho- and para-xylylbis{(N-alkylimidazolidin-2-ylidene)chloro(eta(4)-1,5-cyclooctadiene) rho dium(I)} complexes (2a-d). All compounds synthesized were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of the 2a and 2d were determined by X-ray crystallography. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amount of the new rhodium(I)-carbene complexes (2a-d), to give the corresponding silylethers in good yields (83-99%). Copyright (C) 2008 John Wiley & Sons, Ltd. |
|
| dc.description.abstract |
C1 [Oezdemir, Ismail; Demir, Serpil] Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey. |
|
| dc.description.abstract |
[Sahin, Onur; Bueyuekguengoer, Orhan] Ondokuz Mayis Univ, Dept Phys, TR-55139 Samsun, Turkey. |
|
| dc.description.abstract |
[Cetinkaya, Bekir] Ege Univ, Fac Sci, Dept Chem, TR-35100 Izmir, Turkey. |
|
| dc.source |
APPLIED ORGANOMETALLIC CHEMISTRY |
|
| dc.title |
Synthesis of novel rhodium-xylyl linked N-heterocyclic carbene complexes |
|
| dc.title |
as hydrosilylation catalysts |
|