| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Arslan, H |
|
| dc.contributor.author |
Demir, S |
|
| dc.contributor.author |
VanDerveer, D |
|
| dc.contributor.author |
Cetinkaya, B |
|
| dc.date.accessioned |
2022-10-19T11:01:41Z |
|
| dc.date.available |
2022-10-19T11:01:41Z |
|
| dc.date.issued |
2008 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/82711 |
|
| dc.description.abstract |
A palladium(II) complex, bis[1,3-bis-(2,4,6-trimethylbenzyl)benzimidazol-2 -ylidene]palladium(II) chloride, Pd(NHC), bearing N-heterocyclic carbenes has been synthesized and characterized by elemental analysis, IR spectroscopy and H-1 and C-13 NMR spectroscopy. Crystal structure details of Pd(NHC) are also presented. The palladium centre in the complex lies on a crystallographic inversion centre and occupies a square-planar environment. with both chloride and N-heterocyclic carbene ligands adopting a trans arrangement with Cl-Pd-Cl and C-Pd-C angles are precisely 180 degrees. The palladium-carbene complex was tested as a catalyst in the Suzuki-Miyaura cross-coupling reaction. (c) 2008 Elsevier B.V. All rights reserved. |
|
| dc.description.abstract |
C1 [Arslan, Hakan] Mersin Univ, Dept Chem, Fac Arts & Sci, TR-33343 Mersin, Turkey. |
|
| dc.description.abstract |
[Ozdemir, Ismail; Demir, Serpil] Inonu Univ, Dept Chem, Fac Sci & Arts, TR-44280 Malatya, Turkey. |
|
| dc.description.abstract |
[Arslan, Hakan] Fayetteville State Univ, Dept Nat Sci, Fayetteville, NC 28301 USA. |
|
| dc.description.abstract |
[VanDerveer, Don] Clemson Univ, Dept Chem, Clemson, SC 29634 USA. |
|
| dc.description.abstract |
[Cetinkaya, Bekir] Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey. |
|
| dc.source |
INORGANIC CHEMISTRY COMMUNICATIONS |
|
| dc.title |
Synthesis, characterization and catalytic properties of an |
|
| dc.title |
N-heterocyclic carbene palladium-based complex |
|