| dc.contributor.author |
Yigit, M |
|
| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Cetinkaya, E |
|
| dc.contributor.author |
Cetinkaya, B |
|
| dc.date.accessioned |
2022-10-19T11:24:41Z |
|
| dc.date.available |
2022-10-19T11:24:41Z |
|
| dc.date.issued |
2007 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/82954 |
|
| dc.description.abstract |
Reaction of 1,3-dialkylperhydrobenzimidazolinylidene, 1,3-dialkyl-4-methylimidazolinylidene and 1,3-dialkylimidazolinylidene with [RhCl(COD)](2) yields {1,3-dialkylperhydrobenzimidazolin- 2-ylidene}-, {1,3-dialkyl-4-methylimidazolin- 2-ylidene}- {1,3-dialkylimidazolin-2-ylidene} chloro(eta(4)- 1,5- cyclooctadiene) rhodium(I) complexes (2a-c) and ( 4a, b). All compounds synthesised were characterised by elemental analysis, n.m.r. spectroscopy. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of the new rhodium(I)-carbene complexes (2a-c) and (4a, b), to give the corresponding aryl secondary alcohols in good yield (73-99%). |
|
| dc.description.abstract |
C1 Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44280 Malatya, Turkey. |
|
| dc.description.abstract |
Ege Univ, Dept Chem, TR-35100 Bornova, Turkey. |
|
| dc.source |
TRANSITION METAL CHEMISTRY |
|
| dc.title |
Novel rhodium N-heterocyclic carbene catalysed arylation of aldehydes |
|
| dc.title |
with phenylboronic acid |
|