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Synthesis and catalytic properties of N-functionalised carbene complexes

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dc.contributor.author Ozdemir, I
dc.contributor.author Yigit, M
dc.contributor.author Yigit, B
dc.contributor.author Cetinkaya, B
dc.contributor.author Cetinkaya, E
dc.date.accessioned 2022-10-19T11:24:42Z
dc.date.available 2022-10-19T11:24:42Z
dc.date.issued 2007
dc.identifier.uri http://hdl.handle.net/11616/82976
dc.description.abstract Reaction of [RhCl(COD)] 2, with 1,3-dialkylimidazolinylidene (1) or 1,3-dialkylbenzimidazolinylidene (2) resulted in the formation of rhodium(I) 1,3-dialkylimidazolin-2-ylidene (3a-c) and 1,3-dialkylbenzimidazolin-2-ylidene (4a, b) complexes. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amounts of RhCl(COD)(1,3-dialkylimidazolin-2-ylidene) or RhCl(COD)(1,3-dialkylbenzimidazolin-2-ylidene) to give the corresponding silylethers in good yield (57-98%).
dc.description.abstract C1 Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44280 Malatya, Turkey.
dc.description.abstract Ege Univ, Fac Sci, Dept Chem, TR-35100 Izmir, Turkey.
dc.source JOURNAL OF COORDINATION CHEMISTRY
dc.title Synthesis and catalytic properties of N-functionalised carbene complexes
dc.title of rhodium(I)


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