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Novel azolinium/rhodium system catalyzed addition of arylboronic acids

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dc.contributor.author Ozdemir, I
dc.contributor.author Yigit, M
dc.contributor.author Cetinkaya, E
dc.contributor.author Cetinkaya, B
dc.date.accessioned 2022-10-19T12:05:15Z
dc.date.available 2022-10-19T12:05:15Z
dc.date.issued 2006
dc.identifier.uri http://hdl.handle.net/11616/83432
dc.description.abstract There novel 1,3-dialkylperhydrobenzimidazolinium (2a-c) and two 1,3-dialkylimidazolinium salts (4a,b) as NHC precursors were synthesized from N,N'-dialkyl-1,2-cyclohexanediamine dihydrochloride and 1,2-dialkylpropanediamine dihydrochloride. The in situ prepared three component system [RhCl(COD)](2)/imidazolinium salts (2, 4) and KOBut catalyses the addition of phenylboronic acid to sterically hindered aldehydes affording the corresponding arylated secondary alcohols in good yields.
dc.description.abstract C1 Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44280 Malatya, Turkey.
dc.description.abstract Ege Univ, Dept Chem, TR-35100 Bornova, Turkey.
dc.source HETEROCYCLES
dc.title Novel azolinium/rhodium system catalyzed addition of arylboronic acids
dc.title to aldehydes


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