Preparation and characterization of activated carbons by one-step steam

Abstract

The activated carbons were prepared from Malatya (a city located in the south-east of Turkey) apricot stones by one-step steam pyrolysis/activation process and characterized for their pore structures. Three kinds of apricot stones that differ in their sulfur content, because of the different drying processes, were chosen for this study to investigate the effect of sulfur in the activated carbon production. The effect of process variables, such as activation temperature, soak time, and particle size range was studied on these samples. The activation temperature and time tested were in the ranges of 650-850 degrees C for 1-4 h. The activated carbons were evaluated for their chemical (elemental composition), surface (BET surface area, mercury porosimetry), and adsorption (iodine number) properties. Carbonization behavior of the apricot stones was investigated by thermogravimetric analysis. Scanning electron microscopy (SEM) was used to follow the changes in the carbon texture upon activation.

The experimental results revealed that carbons obtained by the same conditions of activation show differences in their pore structures and adsorption characteristics due to their sulfur contents. The highest BET surface area carbon (1092 m(2)/g) was obtained from the low sulfur content (0.04%) apricot stone with a particle size range of 1-3.35 mm at the activation conditions of 800 degrees C for 4 h. The experimental results showed that commercial production of porous activated carbons from Malatya apricot stones is feasible in Turkey. (c) 2005 Elsevier Inc. All rights reserved.

C1 Inonu Univ, Fac Engn, Dept Chem Engn, TR-44280 Malatya, Turkey.

Penn State Univ, Dept Chem, University Pk, PA 16802 USA.

Izmir Inst Technol, Fac Sci, Dept Chem, TR-35437 Izmir, Turkey.