| dc.contributor.author |
Arslan, H |
|
| dc.contributor.author |
Van Derveer, D |
|
| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Yasar, S |
|
| dc.contributor.author |
Cetinkaya, B |
|
| dc.date.accessioned |
2022-10-19T12:05:24Z |
|
| dc.date.available |
2022-10-19T12:05:24Z |
|
| dc.date.issued |
2006 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/83517 |
|
| dc.description.abstract |
The single crystal X-ray structure of the imidazolidin ruthenium complex, C38H46N2Cl2Ru, was determined. The complex is an orthorhombic space group Pbca with a = 17.3586(32) angstrom, b = 14.4447(27) angstrom, c = 27.4325(52) angstrom, and V = 6878.466(4) angstrom(3) with Z = 8 for D-calc = 1.357 g/cm(3). It exhibits the expected 3-legged piano stool geometry. There is one coordination bond of the ruthenium atom with the electrons of the eta(6)-hexamethylbenzene, 2 symmetrical Ru-Cl bonds, and one Ru-C bond involving the imidazole ring. The coordination around the ruthenium atom is 4-fold, which in this is case is pseudo-tetrahedral. |
|
| dc.description.abstract |
C1 Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA. |
|
| dc.description.abstract |
Mersin Univ, Dept Chem, Fac Arts & Sci, TR-33343 Mersin, Turkey. |
|
| dc.description.abstract |
Clemson Univ, Dept Chem, Clemson, SC 29634 USA. |
|
| dc.description.abstract |
Inonu Univ, Fac Sci & Arts, Dept Chem, Malatya, Turkey. |
|
| dc.description.abstract |
Ege Univ, Fac Sci, Dept Chem, TR-35100 Izmir, Turkey. |
|
| dc.source |
TURKISH JOURNAL OF CHEMISTRY |
|
| dc.title |
Dichloride |
|
| dc.title |
[1-(2,4,6-trimethylbenzyl)-3-(biphenyl-2-ylmethyl)-imidazolidin-2-ylidin |
|
| dc.title |
e (eta(6)-hexamethylbenzene)]ruthenium |
|