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Synthesis of Pd(II) 1-alkylperimidine complexes as efficient catalysts

Synthesis of Pd(II) 1-alkylperimidine complexes as efficient catalysts

Başlık: Synthesis of Pd(II) 1-alkylperimidine complexes as efficient catalysts;
for Suzuki reactions involving arylchlorides
Ozdemir, I; Alici, B; Gurbuz, N; Cetinkaya, B; Cetinkaya, E
Bağlantı: http://hdl.handle.net/11616/83759
Tarih: 2005

Özet:

 
Three palladium(II) complexes of the type [PdCl2(PPh3)L] (L-1-alkylperimidine) have been prepared by reactions of [PdCl2(PR3)]2 with 1-alkylperimidine. The complexes were characterized by conventional spectroscopic methods and elemental analyses. The incorporation of N-coordinated perimidine complexes of palladium(II) gave high catalytic activity in the Suzuki coupling deactivated aryl chloride substrates.
 
C1 Inonu Univ, Fac Sci & Letters, Dept Chem, TR-44069 Malatya, Turkey.
 
Ege Univ, Dept Chem, TR-35100 Izmir, Turkey.
 

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