dc.contributor.author |
Yigit, M |
|
dc.contributor.author |
Ozdemir, I |
|
dc.contributor.author |
Cetinkaya, E |
|
dc.contributor.author |
Cetinkaya, B |
|
dc.date.accessioned |
2022-10-19T12:10:30Z |
|
dc.date.available |
2022-10-19T12:10:30Z |
|
dc.date.issued |
2005 |
|
dc.identifier.uri |
http://hdl.handle.net/11616/83783 |
|
dc.description.abstract |
New 1,3-dialkylperhydrobenzimidazolinium and 1,3-dialkylimidazolinium salts (2,4) as NHC precursors have been synthesized and characterized. These salts in combination with [RhCl(COD)](2) provided active catalysts for the addition of phenylboronic acid to aldehydes under mild conditions. The in situ prepared three-component system [RhCl(COD)](2)/imidazolinium salts (2,4) and KOBu' catalyse the addition of phenylboronic acid to sterically hindered aldehydes affording the corresponding arylated secondary alcohols in good yields. (c) 2005 Wiley Periodicals, Inc. |
|
dc.description.abstract |
C1 Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44280 Malatya, Turkey. |
|
dc.description.abstract |
Ege Univ, Dept Chem, TR-35100 Bornova, Turkey. |
|
dc.source |
HETEROATOM CHEMISTRY |
|
dc.title |
In situ generated rhodium-based catalyst for addition of phenylboronic |
|
dc.title |
acid to aldehydes |
|