| dc.contributor.author |
Yigit, M |
|
| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Cetinkaya, B |
|
| dc.contributor.author |
Cetinkaya, E |
|
| dc.date.accessioned |
2022-10-19T12:10:32Z |
|
| dc.date.available |
2022-10-19T12:10:32Z |
|
| dc.date.issued |
2005 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/83802 |
|
| dc.description.abstract |
Novel rhodium-1,3-dialkylperhydrobenzimidazolin-2-ylidene (2a,b) and 1,3-dialkylimidazolin-2-ylidene complexes (4a,b) have been prepared and characterized by C, H, N analysis, H-1 NMR and C-13 NMR. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amount of the new rhodium(I)-carbene complexes, RhCl(COD)(1,3-dialkylperhydrobenzimidazolin-2-ylidene) or RhCl(COD)(1,3-dialkylimidazolin-2-ylidene) to give the corresponding silylethers in good yields (63-99%). (c) 2005 Elsevier B.V. All rights reserved. |
|
| dc.description.abstract |
C1 Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey. |
|
| dc.description.abstract |
Egfe Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey. |
|
| dc.source |
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL |
|
| dc.title |
Novel N-heterocyclic-carbene-rhodium complexes as hydrosilylation |
|
| dc.title |
catalysts |
|