dc.contributor.author |
Ozdemir, I |
|
dc.contributor.author |
Demir, S |
|
dc.contributor.author |
Cetinkaya, B |
|
dc.contributor.author |
Cetinkaya, E |
|
dc.date.accessioned |
2022-10-19T12:10:33Z |
|
dc.date.available |
2022-10-19T12:10:33Z |
|
dc.date.issued |
2005 |
|
dc.identifier.uri |
http://hdl.handle.net/11616/83814 |
|
dc.description.abstract |
Six new rho dium-tetrahydropyrimidin-2-ylidene complexes (2a-f) have been prepared and characterized by C, H, N analysis, H-1 NMR and C-13 NMR. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of the new rhodium(l)-carbene complexes, RhCl(COD)(1,3-dialkyl-3,4,5,6-tetrahydropyrimidin-2-ylidene), (2a-f), to give the corresponding secondary aryl alcohols in good yields (72-96%). (c) 2005 Elsevier B.V. All rights reserved. |
|
dc.description.abstract |
C1 Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey. |
|
dc.description.abstract |
Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova Yzmir, Turkey. |
|
dc.source |
JOURNAL OF ORGANOMETALLIC CHEMISTRY |
|
dc.title |
Novel rhodium-1,3-dialkyl-3,4,5,6-tetrahydropyrimidin-2-ylidene |
|
dc.title |
complexes as catalysts for arylation of aromatic aldehydes |
|