| dc.contributor.author |
Arslan, H |
|
| dc.contributor.author |
VanDerveer, D |
|
| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Cetinkaya, B |
|
| dc.contributor.author |
Demir, S |
|
| dc.date.accessioned |
2022-10-19T12:10:42Z |
|
| dc.date.available |
2022-10-19T12:10:42Z |
|
| dc.date.issued |
2005 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/83909 |
|
| dc.description.abstract |
Two imidazolidin ruthenium complexes, [RuCl2[N-(2,4,6-trimethyl-benzyl)-N-(n-butyl)]imidazolidin-2-ylidene], 1, and [RuCl2[N-(2,4,6-trimethyl-benzyl)-N-(2-methoxyethyl)]imidazolidin-2-ylidene], 2, have been synthesised and their crystal structures have been determined from single crystal X-ray diffraction data. Compound I is monoclinic, of space group C2/c with a = 18.466(4) angstrom, b = 14.816(3) angstrom, c = 15.413(3) angstrom, beta = 118.067(2)degrees, and V = 3720.9(12) angstrom(3) with Z = 8 for d(calc) = 1.536 g/cm(3). Compound 2 is monoclinic, of space group P2(1)/c with a = 8.1800(5) angstrom, b = 14.344(8) angstrom, c = 14.809(9), beta = 91.604(10)degrees, and V = 1736.7(18) angstrom(3) with Z = 4 for d(calc) = 1.653 g/cm(3). In each complex the ligand functions as an arene and carbene, occupying four coordination sites. The two chlorines in each compound complete a distorted octahedron. |
|
| dc.description.abstract |
C1 Mersin Univ, Fac Arts & Sci, Dept Chem, TR-33343 Mersin, Turkey. |
|
| dc.description.abstract |
Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA. |
|
| dc.description.abstract |
Clemson Univ, Dept Chem, Clemson, SC 29634 USA. |
|
| dc.description.abstract |
Inonu Univ, Fac Sci & Arts, Dept Chem, Malatya, Turkey. |
|
| dc.description.abstract |
Ege Univ, Fac Sci, Dept Chem, Izmir, Turkey. |
|
| dc.source |
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY |
|
| dc.title |
Crystal structure of |
|
| dc.title |
[RuCl2[N-(2,4,6-trimethyl-benzyl)N-(n-butyl)]-imidazolidin-2-ylidene] |
|
| dc.title |
and |
|
| dc.title |
[RuCl2[N-(2,4,6-trimethyl-benzyl)-N-(2-methoxyethyl)]imidazolidin-2-ylid |
|
| dc.title |
ene] |
|