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Synthesis and properties of novel polyimides from dichloro

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dc.contributor.author Seckin, T
dc.contributor.author Koytepe, S
dc.contributor.author Cetinkaya, B
dc.contributor.author Ozdemir, I
dc.contributor.author Yigit, B
dc.date.accessioned 2022-10-19T12:19:04Z
dc.date.available 2022-10-19T12:19:04Z
dc.date.issued 2003
dc.identifier.uri http://hdl.handle.net/11616/84371
dc.description.abstract A novel diamine derivative, dichloro (1,3-p-dimethylaminobenzylimidazolidine-2-ylidene) p-cymene ruthenium (11), bearing a potential site for imide formation, was prepared starting from p-dimethylaminobenzaldehyde. It was used as a monomer to prepare polyimides with several dianhydrides via a one-stage procedure without going through tedious steps. The polyimides have inherent viscosities that range from 1.18 to 1.24 dl/g in N-methyl-2-pyrrolidinone at 30degreesC. These new polymers are soluble in polar aprotic solvents. The polymeric catalyst was added to (Z)-3-methylpent-2-en-4-yn-1-ol without a solvent and the pure furan was isolated by distillation under reduced pressure and GC determined the conversion of the starting enynol.
dc.description.abstract C1 Inonu Univ, Dept Chem, TR-44069 Malatya, Turkey.
dc.description.abstract Ege Univ, Dept Chem, Izmir, Turkey.
dc.source DESIGNED MONOMERS AND POLYMERS
dc.title Synthesis and properties of novel polyimides from dichloro
dc.title (1,3-p-dimethylaminobenzylimidazolidine-2-ylidene) p-cymene ruthenium
dc.title (II)


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