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Synthesis and immobilization of N-heterocyclic carbene complexes of

Synthesis and immobilization of N-heterocyclic carbene complexes of

Başlık: Synthesis and immobilization of N-heterocyclic carbene complexes of;
Ru(II): catalytic activity and recyclability for the furan formation
Cetinkaya, B; Gurbuz, N; Seckin, T; Ozdemir, I
Bağlantı: http://hdl.handle.net/11616/84585
Tarih: 2002

Özet:

 
Synthesis, characterization and immobilization of ruthenium(II) complexes of the type [RuCl2L(eta(6)-arene)] (L=CN(CH2PH)CH2CH2N(CH2)(3)Si(OEt)(3), arene = p-cymene, 3 and arene = C6Me6, 4) and [RuCl2L] (L = eta(1)-carbene-eta(6)-arene bidentate ligand, CN[(CH2)(3)Si(OEt)(3)]CH2CH2NCH2C6H2Me3-eta(6)), 5, morphologically different silicas by sol-gel method are described and their reactivity and recyclability in the furan formation were also reported. (C) 2002 Elsevier Science B.V. All rights reserved.
 
C1 Ege Univ, Dept Chem, TR-35100 Bornova, Turkey.
 
Inonu Univ, Dept Chem, Malatya, Turkey.
 

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