DSpace@İnönü

Synthesis of cis- and trans-dichloro(dimethylphenylphosphine)

Synthesis of cis- and trans-dichloro(dimethylphenylphosphine)

Başlık: Synthesis of cis- and trans-dichloro(dimethylphenylphosphine);
x-(1-methyl-1,4,5,6-tetrahydropyrimidine)platinum(II) and their spectral;
and structural characterization
Cetinkaya, B; Ozdemir, I; Tahir, MN; Ulku, D
Bağlantı: http://hdl.handle.net/11616/84983
Tarih: 1998

Özet:

 
Interaction of [{Pt(mu-Cl)Cl(PMe2Ph)}(2)] with 1-methyl-1,4,5,6-tetrahydropyrimidine, L (R = Me), in boiling toluene produced a mixture of cis- and trans- isomers of [PtCl2(PMe2Ph){N = CH(Me)CH2CH2CH2}] trans-complex 2 isomerizes to give thermody-namically more stable corresponding cis-complex 1 in boiling ethanol. Spectroscopic and X-ray diffraction data permit generalizations about cis- and trans- isomeric pairs to be made. In addition, the trans influence of the ligand L is reliably assessed. (C) 1998 Elsevier Science S.A. All rights reserved.
 
C1 Inonu Univ, Dept Chem, TR-44069 Malatya, Turkey.
 
Hacettepe Univ, Dept Engn Phys, TR-06532 Ankara, Turkey.
 

Tüm öğe kaydını göster

Bu öğenin dosyaları:

Dosyalar Boyut Biçim Göster

Bu öğe ile ilişkili dosya yok.

Bu öğe aşağıdaki koleksiyon(lar)da görünmektedir.