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Catalytic activities in direct arylation of novel palladium N-heterocyclic carbene complexes

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dc.contributor.author Akkoç, Senem
dc.contributor.author Gök, Yetkin
dc.date.accessioned 2020-07-09T10:00:15Z
dc.date.available 2020-07-09T10:00:15Z
dc.date.issued 2014
dc.identifier.citation Akkoç, S., Gök, Y. Catalytic activities in direct arylation of novel palladium N-heterocyclic carbene complexes. (2014). APPLIED ORGANOMETALLIC CHEMISTRY. tr_TR
dc.identifier.issn 0268-2605
dc.identifier.issn 1099-0739
dc.identifier.other DOI: 10.1002/aoc.3220
dc.identifier.uri http://abakus.inonu.edu.tr/xmlui/handle/123456789/16676
dc.description APPLIED ORGANOMETALLIC CHEMISTRY Volume: 28 Issue: 12 Pages: 854-860 DOI: 10.1002/aoc.3220 Published: DEC 2014 Document Type:Article tr_TR
dc.description.abstract Eight novel palladium N-heterocyclic carbene (Pd-NHC) complexes were synthesized by the reaction of chloro 1,3-dialkylbenzimidazolin-2-ylidene silver(I) complexes with bis(benzonitrile)palladium(II) chloride in dichloromethane. These eight Pd-NHC complexes are as follows: bis[1-phenyl-3-(2,4,6-trimethylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-phenyl-3-(2,3,5,6-tetramethylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-phenyl-3-(2,3,4,5,6-pentamethylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-phenyl-3-(3,4,5-trimethoxybenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-(2-diethylaminoethyl)-3-(3-methylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-(2-diethylaminoethyl)-3-(2,3,5,6-tetramethylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II),bis[1-(2-morpholinoethyl)-3-naphthalenomethylbenzimidazol-2-ylidene]dichloropalladium(II) and bis[1-(2-morpholinoethyl)-3-(2-methylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II). Also, these synthesized complexes were fully characterized using Fourier transform infrared, H-1 NMR and C-13 NMR spectroscopic methods and elemental analysis techniques. These synthesized novel Pd-NHC complexes were tested as catalysts in the direct arylation of 2-n-butylthiophene, 2-n-butylfuran and 2-isopropylthiazole with various aryl bromides at 130 degrees C for 1 h. The complexes showed very good catalytic activities in these reactions. Copyright (c) 2014 John Wiley & Sons, Ltd. tr_TR
dc.description.sponsorship Inonu University -- IUBAP 2011/130 tr_TR
dc.language.iso en tr_TR
dc.publisher WILEY tr_TR
dc.subject N-heterocyclic carbene tr_TR
dc.subject aryl bromide tr_TR
dc.subject palladium complex tr_TR
dc.subject direct arylation tr_TR
dc.title Catalytic activities in direct arylation of novel palladium N-heterocyclic carbene complexes tr_TR
dc.type Article tr_TR


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