Yasar, SedatCekirdek, SuzanBinbay, Nil ErtekinTombak, AhmetOcak, Yusuf SelimArslan, NevinBaysal, Akin2024-08-042024-08-0420180030-4026https://doi.org/10.1016/j.ijleo.2017.11.204https://hdl.handle.net/11616/980451,3-Bis(2-morpholinethyl)benzimidazoliumtrichlorido(eta(6)-p-cymene)-ruthenate(11), 2, was synthesized and characterized by NMR spectroscopy and micro analysis. The organic -inorganic heterojunctions were fabricated by using n-type Si wafer and a series of Ru-N-heterocyclic carbene complexes, 3-5, bearing sterically hindered aryl groups were documented for the first time. The thin films of the complexes are deposited on n-Si substrates using spin coating. Current-voltage (I-V) measurements of the devices in dark and illuminated environments were analyzed to determine electrical parameters of devices. Furthermore, the photoelectrical properties of the structures were investigated examined using I-V measurements under a solar simulator. Complexes 3 and 5 showed very low series resistance resulting in high rectification ratios which are promising results for the future electronic and photoelectronic applications. (C) 2017 Published by Elsevier GmbH.eninfo:eu-repo/semantics/closedAccessN-Heterocyclic carbenesRuthenium complexHeterojunctionsElectrical propertiesArticle15651452110.1016/j.ijleo.2017.11.2042-s2.0-85035770276Q2WOS:000424311500066Q3