Özdemir, IDemir, SÇetinkaya, BÇetinkaya, E2024-08-042024-08-0420050022-328X1872-8561https://doi.org/10.1016/j.jorganchem.2005.07.085https://hdl.handle.net/11616/94164Six new rho dium-tetrahydropyrimidin-2-ylidene complexes (2a-f) have been prepared and characterized by C, H, N analysis, H-1 NMR and C-13 NMR. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of the new rhodium(l)-carbene complexes, RhCl(COD)(1,3-dialkyl-3,4,5,6-tetrahydropyrimidin-2-ylidene), (2a-f), to give the corresponding secondary aryl alcohols in good yields (72-96%). (c) 2005 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccesstetrahydropyrimidin-2-ylideneN-heterocyclic carbenearylationrhodiumArticle69024-255849585510.1016/j.jorganchem.2005.07.0852-s2.0-27744538952Q3WOS:000234058600052Q2