Demir, SerpilGokce, YaseminRoisnel, ThierrySortais, Jean-BaptisteDarcel, ChristopheOzdemir, Ismail2024-08-042024-08-0420141631-07481878-1543https://doi.org/10.1016/j.crci.2014.03.015https://hdl.handle.net/11616/96460The new well-defined and air stable anionic iron complexes bearing an imidazolidinium ligand (2a-d) have been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction studies. Starting from FeBr2, [imidazolidinium][FeBr4] complexes 2a and 2b were prepared. The reaction of imidazolidinium chlorides with Fe(OAc)(2), followed by a recrystallization in the air led to bis(imidazolidinium) mu-oxido-bis[trichloroferrate(III)] complexes 2c and 2d. The catalytic activity of these novel complexes has been evaluated in the cross-coupling reactions of alkyl halides with Grignard reagents. (C) 2014 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.eninfo:eu-repo/semantics/openAccessFerrate complexImidazolidinium saltKochi cross-coupling reactionArticle17654154810.1016/j.crci.2014.03.0152-s2.0-84901471243Q3WOS:000337009500007Q2