[Mn(CO)3(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing molecule

Ustun, E.Dusunceli, S. DemirOzdemir, I.2024-08-042024-08-0420170324-1130https://hdl.handle.net/11616/1021533rd International Conference on New Trends in Chemistry -- APR 28-30, 2017 -- Helsinki, FINLANDMetal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important gasotransmitter. We synthesized novel manganese(I) carbonyl complex with general formula [Mn(CO)(3)(bpy)L] OTf (bpy = 2,2'-bipyridyl, L= N-(2-chlorobenzyl) benzimidazole, OTf = SO3CF3). The complex was characterized by LC-MS, H-1 NMR, 2D-COSY NMR, C-13 NMR, IR and elemental analysis. The CO-releasing properties of the complex were investigated. The DFT/TDDFT analyses were also made by ORCA package program.eninfo:eu-repo/semantics/closedAccessCORMcarbonyl complexesmanganese[Mn(CO)3(bpy)(N-2-chlorobenzylbenzimidazole)] OTf complex as a new photoactivatable CO-releasing moleculeConference Object495056WOS:000413538600008Q4