Gurbuz, NevinDemir, SerpilOzdemir, IsmailCetinkaya, BekirBruneau, Christian2024-08-042024-08-0420100040-4020https://doi.org/10.1016/j.tet.2009.12.004https://hdl.handle.net/11616/94946New tetraimidazolinium and tetrabenzimidazolium salts have been prepared Upon reaction with (BuOK)-Bu-t. they generate carbene ligands, which were associated in situ to [RuCp'(MeCN)(3)]PF6 to produce new ruthenium catalysts that are active for the Substitution of allylic substrates by amines, phenols, and carbonucleophiles The influence of the N-heterocyclic core as well as that of the N-substitutents at the periphery of the salts, on reactivity and regioselectivity have been exammed (C) 2009 Elsevier Ltd All rights reservedeninfo:eu-repo/semantics/closedAccessN-Heterocyclic carbene ligandRutheniumAllylationHomogeneous catalysisArticle6661346135110.1016/j.tet.2009.12.0042-s2.0-73649117472N/AWOS:000274591900027Q1