Yigit, BeyhanYigit, MuratOzdemir, Ismail2024-08-042024-08-0420170020-16931873-3255https://doi.org/10.1016/j.ica.2017.07.055https://hdl.handle.net/11616/97911New rhodium(I) N-heterocyclic carbene complexes were synthesized in good yields by the reactions of rhodium dimer [Rh(OMe) COD](2) with two equivalent of 1,3-dialkylimidazolinium chloride salts in tetrahydrofuran. All of the complexes were characterized using elemental analysis, H-1 NMR and C-13 NMR spectroscopy. These complexes were used as catalysts in the hydrosilylation of acetophenone derivatives with triethylsilane at 80 degrees C for h. These Rh(I)-NHC complexes showed the good catalytic performance for the hydrosilylation of acetophenone derivatives and the corresponding hydrosilylation products were obtained in moderate to good yields by using 1 mol% of the rhodium complex. (C) 2017 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessTransition-Metal-ComplexesAsymmetric HydrosilylationTransfer HydrogenationHomogeneous CatalysisCoupling ReactionsOlefin MetathesisRh ComplexLigandsPalladiumAldehydesArticle467757910.1016/j.ica.2017.07.0552-s2.0-85026553317Q2WOS:000410686700011Q2