Arslan, HakanVanDerveer, DonOzdemir, IsmailGurbuz, NevinGok, YetkinCetinkaya, Bekir2024-08-042024-08-0420092056-9890https://doi.org/10.1107/S1600536809000464https://hdl.handle.net/11616/94752The asymmetric unit of the title compound, (C13H15N2S2)-[RuCl3(C10H14)], contains a 1,3-(2-thienylmethyl)-4,5-dihydroimidazolium cation and a trichlorido(eta(6)-p-cymene)ruthenate(II) anion. The thiophene rings of the cation are disordered by an 180 degrees rotation about the thiophene-CH2 bonds with occupancies of 0.847 (5)/0.153 (5) and 0.700 (5)/0.300 (5), respectively. The Ru atom exhibits a distorted octahedral coordination with the benzene ring of the p-cymene ligand formally occupying three sites and three Cl atoms occupying the other three sites. The short C-N bond lengths in the imidazoline ring indicate partial electron delocalization within the N-C-N fragment. Cation and anions are connected through five intermolecular C-H center dot center dot center dot Cl hydrogen bonds and one C-H center dot center dot center dot pi hydrogen bond, forming a three-dimensional hydrogen-bonded network.eninfo:eu-repo/semantics/openAccessN-Heterocyclic CarbenesComplexesCatalystsArylationArticle65M165U4922158177410.1107/S16005368090004642-s2.0-60349105658Q3WOS:000263040700038N/A