Temel, HamdiPasa, SalihOcak, Yusuf SelimYilmaz, IsmailDemir, SerpilOzdemir, Ismail2024-08-042024-08-0420120379-6779https://doi.org/10.1016/j.synthmet.2011.10.018https://hdl.handle.net/11616/95536The thio Schiff base ligand N,N'-bis(o-hydroxy-1-naphtaldehydene)-1,2-bis(o-amino phenilthio)ethane (L) was synthesized by the condensation of o-hydroxy-1-naphthaldehyde and 1,2-bis(2-amino thiophenol)ethane. The reactions of the ligand with different transition metal(II) salts under reflux system condition afforded a series of metal complexes such as Cu(II), Co(III), Ni(II) and Pd(II). Ligand and its complexes were characterized by a combination of elemental analysis, UV-vis spectroscopy, FT-IR, H-1 NMR, MS and TGA/DTA. The electrochemical properties of L and [Cu(L)] were investigated using cyclic voltammetry (CV) in the solutions of dimethyl sulfoxide (DMSO). The catalytic property of thio Schiff base ligand with Suzuki cross-coupling reactions were also determined with different substituted aryl halides in the presence of aryl boronic acid and Pd(AcO)(2) as catalyst. In addition, the fabrication of organic-inorganic hybrid devices using L and its Co(III), Ni(II) and Pd(II) complexes and their electrical properties have been reported. (C) 2011 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccess2-Amino ThiophenolSuzuki couplingCyclic voltammetryOrganic-inorganic heterojunctionArticle16123-242765277510.1016/j.synthmet.2011.10.0182-s2.0-84855896178Q1WOS:000300653700048Q1