Ozdemir, IsmailGurbuz, NevinKaloglu, NazanDogan, OznurKaloglu, MuratBruneau, ChristianDoucet, Henri2024-08-042024-08-0420131860-5397https://doi.org/10.3762/bjoc.9.35https://hdl.handle.net/11616/95976New Pd-NHC complexes have been synthesized and employed for palladium-catalyzed direct arylation of pyrrole derivatives by using electron-deficient aryl chlorides as coupling partners. The desired coupling products were obtained in moderate to good yields by using 1 mol % of these air-stable palladium complexes. This is an advantage compared to the procedures employing air-sensitive phosphines, which have been previously shown to promote the coupling of aryl chlorides with heteroarenes.eninfo:eu-repo/semantics/openAccessaryl chloridesatom-economyC-H bond activationC-H functionalizationcarbenespalladiumpyrrolesArticle93033122350441410.3762/bjoc.9.352-s2.0-84874636250Q2WOS:000315020100001Q2