2-methyl-1,4-benzodioxan-substituted bis(NHC)PdX2 complexes: Synthesis, characterization and the catalytic activity in the direct arylation reaction of some 2-alkyl-heterocyclic compounds

Gok, YetkinAktas, AydinSari, YakupErdogan, Hulya2024-08-042024-08-0420191735-207X1735-2428https://doi.org/10.1007/s13738-018-1512-yhttps://hdl.handle.net/11616/98619Almost in all fields of chemistry, the C-C cross-coupling reactions such as the direct arylation reaction have attracted much attention and have advanced quickly in recent years due to the importance of environment-friendly properties. This study contains the synthesis of the 2-methyl-1,4-benzodioxan-substituted bis(NHC)PdX2 complexes and their catalytic activity in direct arylation reaction. The bis(NHC)PdX2 complexes have been prepared from the 2-methyl-1,4-benzodioxan-substituted Ag(I)NHC complexes via transmetallation method. The bis(NHC)PdX2 complexes have been characterized using H-1 NMR, C-13 NMR, FT-IR spectroscopy and elemental analysis techniques. The bis(NHC)PdX2 complexes have been examined as catalysts in the direct arylation reactions with 2-n-butylfuran, 2-n-butylthiophene and 2-isopropylthiazole, and have demonstrated excellent activity in these reactions.eninfo:eu-repo/semantics/closedAccessN-Heterocyclic carbenesDirect arylationButylfuranButylthiophene2-Isopropylthiazole2-methyl-1,4-benzodioxan-substituted bis(NHC)PdX2 complexes: Synthesis, characterization and the catalytic activity in the direct arylation reaction of some 2-alkyl-heterocyclic compoundsArticle16242343310.1007/s13738-018-1512-y2-s2.0-85060330229Q3WOS:000458026600022Q3