Ustun, ElvanKoc, SefikaDemir, SerpilOzdemir, Ismail2024-08-042024-08-0420160022-328X1872-8561https://doi.org/10.1016/j.jorganchem.2016.05.001https://hdl.handle.net/11616/97310Novel manganese(I) carbonyl complexes of the general formula [Mn(CO)(3)(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-methylbenzyl)imidazoline, N-(3-methylbenzyl)imidazoline, N-(4-methylbenzyl)imidazoline, N-(2,4,6-trimethylbenzyl)imidazoline) were synthesized and characterized by analytical (LC-MS spectrometry and elemental analysis) and spectroscopic (H-1 NMR, C-13 NMR, cosy2D-NMR, infrared) methods. The CO-releasing properties of these complexes were investigated with myoglobin assay. The DFT/TDDFT calculations were made by ORCA package program with both BP86 and B3LYP functionals. (C) 2016 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessCO-releasing moleculesPhotocormsImidazolineManganeseDFT/TDDFTMetal carbonyl complexesArticle815-816162210.1016/j.jorganchem.2016.05.0012-s2.0-84966356691Q3WOS:000376387100003Q2