Karaca, Emine OzgeAkkoc, MitatYasar, SedatOzdemir, Ismail2024-08-042024-08-0420181551-70041551-7012https://doi.org/10.24820/ark.5550190.p010.519https://hdl.handle.net/11616/98449A new series of methyl substituted imidazole-based N-heterocyclic carbene (NHC) palladium complexes (PdCl2(L-1)NHC(L-1 =pyridine) is reported. Structural definitions of Pd-PEPPSI complexes were determined by NMR spectroscopy, elemental analysis and LC-MS spectroscopy techniques. To evolve a more efficient catalytic system for electronically different aryl chloride substrates on the Suzuki cross-coupling reaction, complexes were used as pre-catalyst. Activity of palladium(II)-NHC complexes screened under mild reaction conditions in aqueous media. With this catalytic system, the reaction proceeded in moderate or good yields with low catalyst loading (0.1 mol%). [GRAPHICS] .eninfo:eu-repo/semantics/openAccessSuzuki-Miyaura cross-coupling reactionN-heterocyclic carbenePd-PEPPSI complexC-C bond formationArticle23023910.24820/ark.5550190.p010.5192-s2.0-85052635291Q4WOS:000456008800021Q3