Yigit, MÖzdemir, IÇetinkaya, BÇetinkaya, E2024-08-042024-08-0420051381-11691873-314Xhttps://doi.org/10.1016/j.molcata.2005.07.012https://hdl.handle.net/11616/94124Novel rhodium-1,3-dialkylperhydrobenzimidazolin-2-ylidene (2a,b) and 1,3-dialkylimidazolin-2-ylidene complexes (4a,b) have been prepared and characterized by C, H, N analysis, H-1 NMR and C-13 NMR. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amount of the new rhodium(I)-carbene complexes, RhCl(COD)(1,3-dialkylperhydrobenzimidazolin-2-ylidene) or RhCl(COD)(1,3-dialkylimidazolin-2-ylidene) to give the corresponding silylethers in good yields (63-99%). (c) 2005 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessperhydrobenzimidazolin-2-ylideneimidazolin-2-ylidene N-heterocyclic carbenehydrosilylationrhodiumArticle2411-2889210.1016/j.molcata.2005.07.0122-s2.0-25844526377N/AWOS:000232712200012Q2