Ozdemir, N.Kaloglu, M.Ozdemir, I.2024-08-042024-08-0420230022-47661573-8779https://doi.org/10.1134/S0022476623110094https://hdl.handle.net/11616/101694A PEPPSI-type imidazolidin-2-ylidene-based palladium(II) complex was prepared according to literature. Detail molecular structure of this complex has been confirmed by X-ray diffraction analysis and supplemented by theoretical calculations. Also, electronic properties of the complex were investigated by UV-Vis spectroscopy. The complex under scrutiny was found to adopt a trans arrangement with square-planar geometry. Furthermore, theoretical structure and spectroscopic data were obtained using density functional theory (DFT/HSEH1PBE) method and SDD basis set, and compared with the experimental data. In general, the theoretical findings were in line with the experimental outcomes.eninfo:eu-repo/semantics/closedAccessN-heterocyclic carbenepalladiumPEPPSIX-ray diffractionDFT.Article64112120212910.1134/S00224766231100942-s2.0-85178180108Q4WOS:001110710500011Q4