Dehimat, Zineb ImenePasahan, AzizTebbani, DahmaneYasar, SedatOzdemir, Ismail2024-08-042024-08-0420170040-4020https://doi.org/10.1016/j.tet.2017.08.037https://hdl.handle.net/11616/97955NHC-Pd-PEPPSI complexes with bulky benzyladamantyl substituted N-heterocyclic carbenes (NHC) were synthesized and characterized by NMR, HRMS, and micro analysis. These complexes were then used for Suzuki-Miyaura coupling reactions between aryl bromides and phenylboronic acid. With low catalyst, loading, all synthesized complexes rapidly catalyzed the Suzuki-Miyaura cross-coupling reaction in iPrOH/water (1:3 v/v) at room temperature in air. All palladium compounds were stable and had high catalytic activity for the Suzuki-Miyaura coupling reaction. (C) 2017 Elsevier Ltd. All rights reserved.eninfo:eu-repo/semantics/closedAccessN-heterocyclic carbene complexPalladiumSuzuki couplingGreen chemistrySynthesis of sterically hindered N-benzyladamantyl substituted benzimidazol-2-ylidene palladium complexes and investigation of their catalytic activity in aqueous mediumArticle73405940594510.1016/j.tet.2017.08.0372-s2.0-85028726416Q2WOS:000412036700016Q2