dc.contributor.author |
Kücükbay, Hasan |
|
dc.contributor.author |
Yılmaz, Ülkü |
|
dc.contributor.author |
Yavuz, Kemal |
|
dc.contributor.author |
Buğday, Nesrin |
|
dc.date.accessioned |
2020-10-21T18:26:45Z |
|
dc.date.available |
2020-10-21T18:26:45Z |
|
dc.date.issued |
2015 |
|
dc.identifier.citation |
KÜÇÜKBAY H,YILMAZ Ü,YAVUZ K,BUĞDAY N (2015). Synthesis, characterization, and microwave-assisted catalytic activity in Heck, Suzuki, Sonogashira, and Buchwald{Hartwig cross-coupling reactions of novel benzimidazole salts bearing N-phthalimidoethyl and benzyl moieties. Turkish Journal of Chemistry, 39(6), 1265 - 1278. |
en_US |
dc.identifier.uri |
https://app.trdizin.gov.tr/makale/TWpVNU1UUXhNUT09 |
|
dc.identifier.uri |
http://hdl.handle.net/11616/18464 |
|
dc.description.abstract |
Abstract:Five novel benzimidazole salts ( 1 { 5 ) having N-phthalimidoethyl and 4-substituted benzyl were synthesized and identi ed by 1 H NMR, 13 C NMR, and IR spectroscopic methods and microanalysis. A mixture of the benzimidazole salts ( 1 { 5 ), Pd(OAc) 2 , and K 2 CO 3 in DMF-H 2 O catalyzed, in high yield, the Suzuki{Miyaura and the Heck{Mizoroki cross-coupling reactions assisted by microwave irradiation in 5 min. The novel benzimidazole salts ( 1 { 5 ), Pd(OAc) 2 , Cs 2 CO 3 , PEG, and Cu nanoparticles catalyzed, in high yield, the Sonogashira coupling reaction promoted by microwave irradiation in 10 min. The same benzimidazole salts ( 1 { 5 ), Pd(OAc) 2 , Cs 2 CO 3 , and TBAB catalyzed, in moderate or low yield, the Buchwald{Hartwig reaction assisted by microwave irradiation in 60 min. The efficiency of the catalyst system in these four reactions was discussed as well as the electron-releasing and withdrawing substituent effects on the benzimidazole ligands. |
en_US |
dc.language.iso |
eng |
en_US |
dc.publisher |
Turkish Journal of Chemistry |
en_US |
dc.rights |
info:eu-repo/semantics/closedAccess |
en_US |
dc.title |
Synthesis, characterization, and microwave-assisted catalytic activity in Heck, Suzuki, Sonogashira, and Buchwald{Hartwig cross-coupling reactions of novel benzimidazole salts bearing N-phthalimidoethyl and benzyl moieties |
en_US |
dc.type |
article |
en_US |
dc.relation.journal |
Turkish Journal of Chemistry |
en_US |
dc.contributor.department |
İnönü Üniversitesi |
en_US |