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Chlorido[1-phenyl-3-(2,3,5,6-tetramethylbenzyl)benzimidazol-2-ylidene]si

Chlorido[1-phenyl-3-(2,3,5,6-tetramethylbenzyl)benzimidazol-2-ylidene]si

Başlık: Chlorido[1-phenyl-3-(2,3,5,6-tetramethylbenzyl)benzimidazol-2-ylidene]si;
lver(I)
Akkurt, M; Akkoc, S; Gok, Y; Dagdemir, Y; Tahir, MN
Bağlantı: http://hdl.handle.net/11616/81118
Tarih: 2012

Özet:

 
In the title compound, [AgCl(C24H24N2)], the terminal phenyl and tetramethylbenzene rings [which form a dihedral angle of 87.92 (14)degrees] make dihedral angles of 59.59 (11) and 83.19 (12)degrees with respect to the central benzimidazole ring system. The Ag-C and Ag-Cl single-bond lengths are 2.087 (3) and 2.3267 (9)degrees. The C-Ag-Cl bond angle is 172.84 (7)degrees. C-H center dot center dot center dot pi interactions contribute to the stabilization of the crystal structure. A very weak pi-pi stacking interaction between adjacent tetramethylbenzene rings [centroid-centroid distance = 4.0610 (18) angstrom] is also observed.
 
C1 [Akkurt, Mehmet; Dagdemir, Yilmaz] Erciyes Univ, Dept Phys, Fac Sci, TR-38039 Kayseri, Turkey.
 
[Akkoc, Senem] Erciyes Univ, Fac Sci, Dept Chem, TR-38039 Kayseri, Turkey.
 
[Gok, Yetkin] Inonu Univ, Dept Chem, Fac Arts & Sci, TR-44280 Malatya, Turkey.
 
[Tahir, Muhammad Nawaz] Univ Sargodha, Dept Phys, Sargodha, Pakistan.
 

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