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Dichlorido[1-(2-methylbenzyl)-3-(eta(6)-2,4,6-trimethylbenzyl)-1H-2,3-di

Dichlorido[1-(2-methylbenzyl)-3-(eta(6)-2,4,6-trimethylbenzyl)-1H-2,3-di

Title: Dichlorido[1-(2-methylbenzyl)-3-(eta(6)-2,4,6-trimethylbenzyl)-1H-2,3-di;
hydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate
Arslan, H; VanDerveer, D; Yasar, S; Ozdemir, I; Cetinkaya, B
URI: http://hdl.handle.net/11616/82417
Date: 2009

Abstract:

 
The title complex, [RuCl2(C25H26N2)]center dot CH2Cl2, is best thought of as containing an octahedrally coordinated Ru center with the arene occupying three sites. Two Ru-Cl bonds and one Ru-carbene bond complete the distorted octahedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C6H2(CH3)(3) arene group by a CH2 bridge. This leads to a system with very little apparent strain. A dichloromethane solvent molecule completes the crystal structure. Further stabilization is accomplished via C-center dot center dot center dot N and C-H center dot center dot center dot Cl interactions.
 
C1 [Arslan, Hakan] Fayetteville State Univ, Dept Nat Sci, Fayetteville, NC 28301 USA.
 
[Arslan, Hakan] Mersin Univ, Fac Pharm, Dept Chem, TR-33169 Mersin, Turkey.
 
[VanDerveer, Don] Clemson Univ, Dept Chem, Clemson, SC 29634 USA.
 
[Yasar, Sedat; Ozdemir, Ismail] Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44280 Malatya, Turkey.
 
[Cetinkaya, Bekir] Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey.
 

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