| dc.contributor.author |
Arslan, H |
|
| dc.contributor.author |
VanDerveer, D |
|
| dc.contributor.author |
Yasar, S |
|
| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Cetinkaya, B |
|
| dc.date.accessioned |
2022-10-19T09:38:58Z |
|
| dc.date.available |
2022-10-19T09:38:58Z |
|
| dc.date.issued |
2009 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/82417 |
|
| dc.description.abstract |
The title complex, [RuCl2(C25H26N2)]center dot CH2Cl2, is best thought of as containing an octahedrally coordinated Ru center with the arene occupying three sites. Two Ru-Cl bonds and one Ru-carbene bond complete the distorted octahedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C6H2(CH3)(3) arene group by a CH2 bridge. This leads to a system with very little apparent strain. A dichloromethane solvent molecule completes the crystal structure. Further stabilization is accomplished via C-center dot center dot center dot N and C-H center dot center dot center dot Cl interactions. |
|
| dc.description.abstract |
C1 [Arslan, Hakan] Fayetteville State Univ, Dept Nat Sci, Fayetteville, NC 28301 USA. |
|
| dc.description.abstract |
[Arslan, Hakan] Mersin Univ, Fac Pharm, Dept Chem, TR-33169 Mersin, Turkey. |
|
| dc.description.abstract |
[VanDerveer, Don] Clemson Univ, Dept Chem, Clemson, SC 29634 USA. |
|
| dc.description.abstract |
[Yasar, Sedat; Ozdemir, Ismail] Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44280 Malatya, Turkey. |
|
| dc.description.abstract |
[Cetinkaya, Bekir] Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey. |
|
| dc.source |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
|
| dc.title |
Dichlorido[1-(2-methylbenzyl)-3-(eta(6)-2,4,6-trimethylbenzyl)-1H-2,3-di |
|
| dc.title |
hydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate |
|