| dc.contributor.author |
Cetinkaya, B |
|
| dc.contributor.author |
Ozdemir, I |
|
| dc.contributor.author |
Tahir, MN |
|
| dc.contributor.author |
Ulku, D |
|
| dc.date.accessioned |
2022-10-19T12:48:41Z |
|
| dc.date.available |
2022-10-19T12:48:41Z |
|
| dc.date.issued |
1998 |
|
| dc.identifier.uri |
http://hdl.handle.net/11616/84983 |
|
| dc.description.abstract |
Interaction of [{Pt(mu-Cl)Cl(PMe2Ph)}(2)] with 1-methyl-1,4,5,6-tetrahydropyrimidine, L (R = Me), in boiling toluene produced a mixture of cis- and trans- isomers of [PtCl2(PMe2Ph){N = CH(Me)CH2CH2CH2}] trans-complex 2 isomerizes to give thermody-namically more stable corresponding cis-complex 1 in boiling ethanol. Spectroscopic and X-ray diffraction data permit generalizations about cis- and trans- isomeric pairs to be made. In addition, the trans influence of the ligand L is reliably assessed. (C) 1998 Elsevier Science S.A. All rights reserved. |
|
| dc.description.abstract |
C1 Inonu Univ, Dept Chem, TR-44069 Malatya, Turkey. |
|
| dc.description.abstract |
Hacettepe Univ, Dept Engn Phys, TR-06532 Ankara, Turkey. |
|
| dc.source |
JOURNAL OF ORGANOMETALLIC CHEMISTRY |
|
| dc.title |
Synthesis of cis- and trans-dichloro(dimethylphenylphosphine) |
|
| dc.title |
x-(1-methyl-1,4,5,6-tetrahydropyrimidine)platinum(II) and their spectral |
|
| dc.title |
and structural characterization |
|