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    The modification of aluminium tri-sec-butoxide with different alcohols and chelating ligands: Hydrolysis and condensation of the products
    (Marcel Dekker Inc, 1997) Sayilkan, H; Arpac, E; Sener, E
    In this work, alcoholysis reactions of aluminium-sec-butoxide, Al(OBu-s)(3), with 2-ethoxyethanol (EtOCH2CH2OH) and 2-butoxyethanol (BuOCH2CH2OH), complexation reactions of Al(OBu-s)(3) and of alcohol-modified Al(OBu-s)(3) with methacrylic acid (MAC) and ethyl acetoacetate (EAAH), and the hydrolysis reactions of Al(OBu-s)(3) and modified Al(OBu-s)(3) are studied in some detail. Alcoholysis reactions of Al(OBu-s)(3) were performed with different mole ratios of 2-ethoxyethanol and 2-butoxyethanol at room temperature and combining ratios were found to be 1:3 [Al(OBu-s)(3):alcohol] by H-1 NMR analyses. Al(OBu-s)(3) and alcohol-modified Al(OBu-s)(3) were reacted at room temperature with equimolar amounts of methacrylic acid and ethyl acetoacetate and the products were characterized by H-1 NMR, GC, FT-IR and elemental analyses. Hydrolysis-condensation reactions of the various compounds thus formed were studied in detail and the products were characterized by gas chromatography, Karl Fisher coulometric titrations, thermal analysis and FT-IR.
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    Synthesis, characterization and applications of sol-gel derived zirconium oxide adsorbent powder: Removal from aqueous solution of phenol and p-chlorophenol
    (Tubitak Scientific & Technological Research Council Turkey, 2003) Akarsu, M; Sayilkan, H; Sener, A; Sayilkan, F; Arpac, E
    Adsorbent powders were prepared from the uncatalysed hydrolysis-condensation reactions of different complexes that were synthesized by the reactions of Zr(OPrn)(4) with different chelating ligands (such as allylacetic acid [AAH], vinylacetic acid [VAH] and citraconic acid [CAH]). The complex products were characterized by FT-IR, H-1-NMR and C-13-NMR spectra. The maximum combination ratios of AAH/Zr(OPrn)(4), VAH/Zr(OPrn)(4) and CAH/Zr(OPrn)(4) were 1.7, 0.9 and 1.3, respectively. The hydrolysis-condensation products of these complexes were calcinated at 900 degreesC and half of them were coated with 3-glycidyloxypropyltrimethoxysilane (GLYMO). The surface area and average pore diameter of the powders were estimated by the analysis of adsorption/desorption BET isotherm data. The adsorption capacities of these powders for aqueous phenol and p-chlorophenol were calculated following spectrophotometric determination. Phenol and p-chlorophenol adsorption on all of the GLYMO-coated adsorbents were satisfactory, e.g., the adsorbent obtained from the hydrolyzed, calcinated and GLYMO-coated form of Zr(OPrn)(2.3)(AA)(1.7) adsorbed 63% of phenol while the uncoated form adsorbed only 10%. The adsorption isotherm has been determined and data have been analyzed according to the Freundlich model.