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Öğe Electrochemical Corrosion and Metal Ion Release Protective Efficiency of the Multilayer TaN Coatings on CoCrMo Biomedical Alloy(Kaunas Univ Tech, 2021) Aslan, Ali Kemal; Bahce, Erkan; Guler, Mehmet SamiCoCrMo alloy is widely used in artificial orthopedic joint applications due to its high mechanical properties. But, high levels of the metal ion release from alloy surfaces cause variable toxic and allergic effects on the patient in vivo use. This case restricts the lifetime of the implant and results in the failure of the artificial joint. In order to enhance the corrosion resistance and to decrease the metal ion release, alloy surface was multilayer-coated by closed field unbalanced magnetron system. The protective efficiency of the coatings was determined by potentiodynamic polarization tests and static immersion tests were performed for 45, 60 and 90 days in the simulated body fluid in order to understand the effect of the coatings on the metal ion release. The metal ion concentrations in the simulated body fluids were determined by using inductively coupled plasma mass spectrometry device. The electrochemical corrosion results showed that the multilayer coatings provided 93 % protective efficiency in terms of corrosion resistance. Multilayer coatings decreased the metal ions release levels significantly, especially Co leaking was decreased approximately 52 times compared to uncoated samples.Öğe WEAR AND ADHESION PROPERTIES OF MULTILAYER Ti/TiN, (/TiC)/ TiCN/ TaN THIN FILMS DEPOSITED ON Ti13Nb13Zr ALLOY BY CLOSED FIELD UNBALANCED MAGNETRON SPUTTERING(Scicell Sro, 2023) Aslan, Ali Kemal; Bahce, ErkanTi13Nb13Zr alloy stands out as an alternative to Ti6Al4V alloy for orthopaedic joint implant applications due to its low modulus of elasticity, high mechanical properties, high corrosion resistance, high biocompatibility and low modulus of elasticity, as well as con-taining no cytotoxic elements. In this study, Ti13Nb13Zr alloy was coated with TiN/TiC/TiCN/TaN multilayer thin films by pulsed -dc CFBUMS method to increase wear resistance and improve surface properties. Characterization of the deposited films were con-ducted by XRD, SEM, AFM, pin-on-disk, progressive scratch experiments. As a result, it is observed that all the coatings enhanced the tribological properties of the Ti13Nb13Zr alloy surface. The 20-layer TiN/TiC/TiCN/TaN multilayer coatings gave the best results for wear resistance and adhesion properties. Enhancing the interlayer number resulted in increased wear and adhesion resistance. In addition, it was determined that using TiC instead of TiN in the interlayers gave higher results regarding adhesion, wear, and mechan-ical properties.