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Öğe Biosorption of copper(II) by live and dried biomass of the white rot fungi Phanerochaete chrysosporium and Funalia trogii(Wiley-V C H Verlag Gmbh, 2005) Kahraman, S; Asma, D; Erdemoglu, S; Yesilada, OBiosorption is an innovative and alternative technology to remove heavy metal pollutants from aqueous solution using live, inactive and dead biomasses such as algae, bacteria and fungi. In this study, live and dried biomass of Phanerochaete chrysosporium and Funalia trogii was applied as heavy metal adsorbent material. Biosorption of copper(II) cations in aqueous solution by live and dried biomass of Phanerochaete chrysosporium and Funalia trogii was investigated to study the effects of initial heavy metal concentration, pH, temperature, contact time, agitation rate and amount of fungus. Copper(II) was taken up quickly by fungal biomass (live or dried) during the first 15 min and the most important factor which affected the copper adsorption by live and dried biomass was the pH value. An initial pH of around 5.0 allowed for an optimum adsorption performance. Live biomass of two white rot fungi showed a high copper adsorption capacity compared with dried biomass. Copper(II) uptake was found to be independent of temperature in the range of 20-45degreesC. The initial metal ion concentration (10-300 mg/L) significantly influenced the biosorption capacity of these fungi. The results indicate that a biosorption as high as 40-60% by live and dried biomass can be obtained under optimum conditions.Öğe Characterization and photocatalytic properties of TiO2-nanosols synthesized by hydrothermal process at low temperature(Elsevier, 2006) Sayilkan, F; Asiltürk, M; Erdemoglu, S; Akarsu, M; Sayilkan, H; Erdemoglu, M; Arpaç, ETransparent nanocrystalline pure anatase titania (nano-TiO2) was synthesized by hydrothermal process at 200 degrees C. Photocatalytic activity of the nano-TiO2 as in the form of sol was tested for degradation of Methylene Blue (MB) and Reactive Red 120 (RR-120) in aqueous solutions. Structural and physico-chemical properties of the nano-TiO2 were characterized using powder XRD, SEM, BET, FTIR and elemental analyses. Complete photodegradation of RR-120 was successfully achieved by aid of the nano-TiO2 whereas NIB was not degraded, maybe because of reversible color change in nano-TiO2 sol/MB mixture after the LTV irradiation was stopped. Potocatalytic activity of the synthesized the nano-TiO2 for degradation of RR-120 was compared with Degussa P-25 at optimum conditions determined for RR-120. It was found that the nano-TiO2 can be repeatedly used with higher photocatalytic activity than Degussa P-25. (c) 2005 Elsevier B.V All rights reserved.Öğe Characterization of the hydrothermally synthesized nano-TiO2 crystallite and the photocatalytic degradation of Rhodamine B(Elsevier, 2006) Asiltürk, M; Sayilkan, F; Erdemoglu, S; Akarsu, M; Sayilkan, H; Erdemoglu, M; Arpaç, EPure anatase-TiO2 nanoparticles with 8 nm average crystallite size was synthesized hydrothermally at 200 degrees C in 2 h. The structural and physicochemical properties of nano-TiO2 were determined by powder XRD, FT-IR, BET and SEM analyses. The behavior of anatase nano-TiO2 in catalytic degradation of Rhodamine B (RB) dye in transparent nano-TiO2 sol under UV-light was examined as a function of irradiation power of UV-Iight, irradiation time, amount of nano-TiO2 and initial RB concentration in the sol. Rhodamine B was fully degraded with the catalysis of the nano-TiO2 in a short time as low as 60 min. Photocatalytic activity of the nano-TiO2 for degradation of RB was compared with Degussa P-25 at optimum catalysis conditions determined for the nano-TiO2. It was found that, when compared to Degussa P-25, the nano-TiO2 could be repeatedly used with increasing photocatalytic activity. It was found that the photodegradation obeys the pseudo first-order reaction kinetics with the rate constant of 0.0658 min(-1), and the half period t(1/2) was 10.53 min. (c) 2005 Elsevier B.V. All rights reserved.Öğe Natural pyrophyllite and M(OR)x based MxOy powders as new adsorbents for heavy metal adsorption(Trans Tech Publications Ltd, 2004) Erdemoglu, M; Sayilkan, F; Erdemoglu, S; Sener, S; Akarsu, M; Sayilkan, HHeat treated hydrolysis-condensation products of aluminiumtri-sec-butoxide (Al(OBus)(3)) and alcohol modified Al(OBus)(3) were synthesised by sol-gel process. These synthetic powders, natural pyrophyllite and their 3-mercaptoprophyltrimethoxysilane coated forms were utilised as adsorbents for the removal of Cu(II) ions from aqueous solutions. The adsorption increased when natural and synthetic powders coated with SH-Si were used. It was concluded that the dried powders obtained from the hydrolysis-condensation product of Al(OBus)(3) and its alcohol modified form, and coated pyrophyllite would substitute for Amberlite IR 120 Na form resin.Öğe New adsorbents from Ti(OPrn)4 by the sol-gel process: Synthesis, characterization and application for removing some heavy metal ions from aqueous solution(Tubitak Scientific & Technological Research Council Turkey, 2004) Sayilkan, F; Sayilkan, H; Erdemoglu, S; Sener, S; Akarsu, MNew adsorbents were synthesized by the sol-gel process from the product of a hydrolysis reaction and its coated form of titanium(IV)-n-propoxide for removing some heavy metal ions from aqueous solution. Titanium(IV)-n-propoxide was uncatalyst hydrolyzed with different amounts of water at room temperature and was found to react in a 1:1.6 ratio (mole of Ti:mole of H2O). It was found that the condensation following the hydrolysis reflection was alcohol condensation. The hydrolysis-condensation product was characterized in detail by GC. Karl-Fischer coulometric titrator, NIR-spectroscopy, FT-IR spectroscopy, TG-DTA and elemental analysis. The hydrolysis-condensation product of titanium(TV)-n-propoxide was calcinated at 900degreesC after drying at 100degreesC and some of this product was coated with hydrolyzed NH2-functional silanes [3-(2-aminoethylamino)ethylamino)propyl-trimethoxy silane] (Amino-and [3-(2-aminoethylamino)propylmethyldimetoxysilane] (Amino-2), separately. Adsorption capacities of uncoated and NH2-functional silane coated hydrolysis-condensation products for Fe3+, Cu2+ and Pb2+ ions in aqueous solution were investigated by FAAS. It was observed that the extent of adsorption was influenced significantly by the type and concentrations of coating materials, e.g., Amino-1 coated adsorbent prepared in methyl alcohol as 50% (w/w) and 100% (without methyl alcohol) adsorbed 90-67% and 100% of Fe3+, respectively. while the uncoated form adsorbed only 5%. The adsorption isotherm was determined and the data were analyzed according to the Freundlich model.Öğe Organo-functional modified pyrophyllite: preparation, characterisation and Pb(II) ion adsorption property(Elsevier, 2004) Erdemoglu, M; Erdemoglu, S; Sayilkan, F; Akarsu, M; Sener, S; Sayilkan, HSurface modification of clay minerals has become increasingly important for improving the practical applications of clays such as fillers and adsorbents. In this study, the surface of pyrophyllite mineral was modified by coating with 3-(2-aminoethylamino) propyl-methyidimethoxysilane (APMDS) coupling agent and utility of the APMDS-modified pyrophyllite was investigated as an adsorbent for removal of Pb(II) ions from aqueous solutions. XRD, FT-IR and SEM analysis were used to characterise the surface modification and it was suggested that hydrogen bonding takes place between the hydroxyl groups and/or oxygen atoms within the structure of pyrophyllite and hydroxyl groups of APMDS. The APMDS-modified pyrophyllite adsorbed approximately 93% of Pb(II) ions at an initial concentration of 20 mg/l, while natural pyrophyllite did only 35% under the same conditions. The adsorption of Pb(II) increased with increasing pH and reached a maximum value in the pH range 6.5-7. The effects of various factors on the adsorption, such as pH of the solution, contact time, amount of adsorbent and initial Pb(II) concentration, were studied. The adsorption isotherm has been determined and data have been analysed according to the Langmuir model and found to be favourable, i.e., the separation parameter is less than unity (R-L < 1). (C) 2003 Elsevier B.V. All rights reserved.Öğe Removal of inorganic-organic bound Cu(II) from different aqueous solutions by new adsorbents synthesized by sol-gel process(Taylor & Francis Inc, 2004) Erdemoglu, S; Sayilkan, F; Emre, FB; Akarsu, M; Sener, S; Sayilkan, HHydrolysis product of alcohol modified titanium(IV)-n-propoxide and its coated form were prepared as new and regenerable adsorbents for adsorbing and removing Cu(II) ions from its different aqueous solutions. The hydrolysis and alcoholysis products and adsorbents were characterized using GC, H-1-NMR, FT-IR, SEM, and TG-DTA analysis. It was found that Cu(II) ion adsorption rather increased when hydrolysis product of alcohol modified titanium(IV)-n-propoxide was coated with prehydrolyzed 3-mercaptopropyltrimethoxy silane in n-propanol and this coated material was used as adsorbent. Depending on the results of experiments performed at optimum conditions of initial Cu(II) concentration, amount of adsorbent, contact time, and pH, maximum adsorption of Cu(II), i.e., >98% has been achieved under the non-competitive conditions, while almost 60% is achieved under the competitive conditions of Pb(II), Zn(II), Fe(III), and alkali and earth alkali metals. It was also concluded that Cu(II) adsorption efficiency is not affected from the media containing acetate, tannic acid, or Turkish Blue dye. The adsorbent was easily regenerated with 5 N HNO3 solution and used over and over again for the adsorption of Cu(II) ions.Öğe The removal of Pb2+, Cu2+ and Fe3+ from aqueous solution by a new adsorbent synthesized from Ti(OPrn)4 by sol-gel process(Parlar Scientific Publications (P S P), 2003) Erdemoglu, S; Sayilkan, F; Akarsu, M; Sener, S; Sayilkan, HRemoval of Cu(II), Pb(II) and Fe(III) ions from aqueous solutions was studied by using a new adsorbent synthesised by hydrolysis and subsequent condensation of Ti(OPrII)(4) by sol-gel process. Metal ion adsorption was highly increased when the adsorbent surface was covered with a coating solution of hydrolysed NH2- and SH-functional silanes prepared in methanol. Adsorption conditions for Cu, Pb and Fe ions were optimized. It was concluded that Cu was retained to 100% on SH-functional silane coated adsorbents, whereas Fe(III) and Pb(II), 89% and 100%, resp., on NH2-functional silane coated adsorbents.Öğe Surface modification of pyrophyllite with amino silane coupling agent for the removal of 4-nitrophenol from aqueous solutions(Academic Press Inc Elsevier Science, 2004) Sayilkan, H; Erdemoglu, S; Sener, S; Sayilkan, F; Akarsu, M; Erdemoglu, MThe surface of naturally hydrophobic mineral pyrophyllite was modified to hydrophilic by treatment with prehydrolyzed N-(2-aminoethyl)3-ammopropyltrimethoxysilane (APEO) coupling agent to prepare a novel and effective adsorbent for the removal of 4-nitrophenol (4-NP) from aqueous solutions. XRD, FTIR, and SEM analyses were used to characterize the surface modification. It was found that after the grafting procedure, heat treatment at 110 degreesC results in condensation reaction between the OH groups of the APEO molecule and the hydroxyl groups and/or oxygen atoms on the pyrophyllite surface and the adsorption of 4-NP by APEO-modified pyrophyllite involves interactions between dissociated 4-NP molecules and protonated amine groups of APEO molecules attached to the mineral surface. Adsorption equilibrium data for 4-NP adsorption on APEO-treated and untreated pyrophyllite were most satisfactorily fitted using the Freundlich adsorption isotherm and adsorption capacity was found to be 0.268 mg/g for modified pyrophyllite whereas it was only 0.105 mg/g for untreated pyrophyllite. (C) 2004 Elsevier Inc. All rights reserved.