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    Polymerization capacity of orthodontic composites analyzed by Fourier transform infrared spectroscopy
    (Mosby-Elsevier, 2011) Corekci, Bayram; Malkoc, Siddik; Ozturk, Bora; Gunduz, Beniz; Toy, Ebubekir
    Introduction: The aim of this in-vitro study was to analyze the polymerization capacity of 5 orthodontic composites by determining the degree of monomer conversion (DC). Methods: Fourier transform infrared spectroscopy was used to evaluate the DC of the orthodontic composites immediately after polymerization and after storage in artificial saliva at 37 degrees C +/- 1 degrees C for 30 days. The resin-based adhesive composites investigated were Bisco Ortho (Bisco, Schaumburg, III), Heliosit Orthodontics (Ivoclar, Schaan, Liechtenstein), Kurasper F (Kuraray, Okayama, Japan), Light Bond (Reliance Orthodontic Products, Itasca, III), and Transbond XT (3M Unitek, Monrovia, Calif), cured with Elipar FreeLight 2 (3M ESPE, St Paul, Minn) for the testing of the DC values. Fifty cylindrical specimens were manufactured in molds. The data were analyzed by 2-factor analysis of variance (ANOVA) and Tukey HSD test. Results: According to 2-way ANOVA, the DC was significantly influenced by composite type (P < 0.05); after 30 days, there were no differences among the composite types for the DC. The interaction of orthodontic composites and time played a statistically significant role in the DC (P < 0.05), but there was no statistically significant influence of time for the DC (P > 0.05). Conclusions: The DC was found to change according to composite materials used, and Bisco Ortho showed the most DC performance. The DC of orthodontic composites is a complex process that is affected not only by inorganic filler content of the composite but also the monomer type and many other factors. Sufficient DC values of 5 commercially available orthodontic composites can be achieved with a new-generation light-emitting diode curing light. (Am J Orthod Dentofacial Orthop 2011;139:e299-e304)

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