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    Transfer Hydrogenation of Ketones by Ruthenium Complexes Bearing Benzimidazol-2-ylidene Ligands
    (Wiley-V C H Verlag Gmbh, 2010) Gurbuz, Nevin; Yasar, Sedat; Ozcan, Emine Oezge; Ozdemir, Ismail; Cetinkaya, Bekir
    A series of benzimidazolium ligand precursors were metalated with [RuCl2(p-cymene)](2) to give ruthenium(II) N-heterocyclic carbene complexes. All compounds were fully characterized by elemental analyses, H-1 NMR, C-13 NMR, and IR spectroscopy. The new benzimidazol-2-ylidene complexes have been found to be effective catalysis for the transfer hydrogenation of ketones by using 2-propanol as the hydrogen source in the presence of KOH.