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Öğe 1,3-Bis(3-phenylpropyl)-1H-benzimidazole-2(3H)-tellurone(Blackwell Publishing, 2008) Yalcin, Serife Pinar; Akkurt, Mehmet; Yilmaz, Uelkue; Kucukbay, Hasan; Buyukgungor, OrhanThe title compound, C25H26N2Te, was synthesized from bis[1,3-bis(3-phenylpropyl)benzimidazolidin-2-ylidene] and Te in a toluene solution. The molecule possesses a twofold rotation axis passing through the Te atom and the center of the benzimidazole ring system. The benzimidazole ring system makes an angle of 67.9 (4) with the phenyl rings.Öğe Synthesis and microwave-assisted catalytic activity of novel bis-benzimidazole salts bearing furfuryl and thenyl moieties in Heck and Suzuki cross-coupling reactions(Wiley-Blackwell, 2010) Yilmaz, Uelkue; Sireci, Nihat; Deniz, Selma; Kucukbay, HasanA mixture of bis-benzimidazole salts (1-7), Pd(OAc)(2) and K(2)CO(3) in DMF-H(2)O catalyzes, in high yield, the Suzuki and Heck cross-coupling reactions assisted by microwave irradiation in a short time. In particular, the yields of the Heck and Suzuki reactions with aryl bromides were found to be nearly quantative. The synthesized bis-benzimidazole salts (1-7) were identified by (1)H-(13)C NMR, IR spectroscopic methods and micro analysis. Copyright (C) 2010 John Wiley & Sons, Ltd.