2-(2,6-DI-TERT-BUTYLPHENOXY)-2',4,4,4',4',6,6,6',6'-NONACHLORO-2,2'-BI(CYCLOTRI-LAMBDA-5-PHOSPHAZENE)
Küçük Resim Yok
Tarih
1994
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Munksgaard Int Publ Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The title compound consists of the bulky 2,6-di-tert-butylphenoxy group and two phosphazene rings joined by a P-P bond [2.193 (2) angstrom]. The bulky group plays a predominant role in the distortion of the molecule as a whole. This distortion results in deviations of the benzene and phosphazene rings from planarity and twists the rings with respect to each other. In monocyclophosphazenes, the endocyclic angles about the P atom decrease while the exocyclic angles increase. This is in contrast to the behaviour of title compound (a bicyclophosphazene) in which the exo- and endocyclic angles about the P atoms both decrease on substitution.
Açıklama
Anahtar Kelimeler
Phosphorus Nitrogen-Compounds, Transition-Metal Derivatives, Structural Investigations, Solid-State, X-Ray, Conformation, Crystal
Kaynak
Acta Crystallographica Section C-Crystal Structure Communications
WoS Q Değeri
N/A
Scopus Q Değeri
Cilt
50
