First ruthenium complexes with a chelating arene carbene ligand as catalytic precursors for alkene metathesis and cycloisomerisation

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.authorwosidTOUPET, Loic/N-7043-2014
dc.contributor.authorÇetinkaya, B
dc.contributor.authorDemir, S
dc.contributor.authorÖzdemir, I
dc.contributor.authorToupet, L
dc.contributor.authorSémeril, D
dc.contributor.authorBruneau, C
dc.contributor.authorDixneuf, PH
dc.date.accessioned2024-08-04T20:58:51Z
dc.date.available2024-08-04T20:58:51Z
dc.date.issued2001
dc.departmentİnönü Üniversitesien_US
dc.description.abstractElectron-rich carbene precursors 2 and 3, containing the imidazolidin-2-ylidene moiety with one (2) and two (3) pendent N-(2,4,6-trimethylbenzyl) groups, on reaction with [RuCl2(arene)](2) lead to ruthenium(II) complexes 5 and 6 containing the chelating 8-electron mixed arene-carbene ligand; the X-ray diffraction crystal structure of RuCl2{eta (1)- CN[CH2(eta (6)-2,4,6-Me3C6H2)]CH2CH2N(CH2CH2OMe)} 6, was established. These complexes are precursors of the unstable ruthenium-allenylidene intermediates 7 and 8, but are active catalysts either for selective catalytic alkene metathesis or cycloisomerization, depending on the nature of the 1,6-diene.en_US
dc.identifier.doi10.1039/b100264n
dc.identifier.endpage521en_US
dc.identifier.issn1144-0546
dc.identifier.issn1369-9261
dc.identifier.issue4en_US
dc.identifier.startpage519en_US
dc.identifier.urihttps://doi.org/10.1039/b100264n
dc.identifier.urihttps://hdl.handle.net/11616/103217
dc.identifier.volume25en_US
dc.identifier.wosWOS:000168255600001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofNew Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic Carbenesen_US
dc.subjectOlefin Metathesisen_US
dc.subjectCrossen_US
dc.subjectPalladium(Ii)en_US
dc.titleFirst ruthenium complexes with a chelating arene carbene ligand as catalytic precursors for alkene metathesis and cycloisomerisationen_US
dc.typeArticleen_US

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