HIGH PROBABILITY OF LARGE ORBITAL ANGULAR MOMENTUM CONTRIBUTION TO THE MAGNETIC MOMENT OF COBALT(II) ION IN NEWLY REPORTED MACROCYCLIC COMPLEX CONTAINING AMIDE, IMINE AND SECONDARY AMINE FUNCTIONS

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dc.authoridAytekin, Ozlem/0000-0002-4366-7847
dc.authorwosidbayri, ali/AAA-5966-2021
dc.contributor.authorBayri, Ali
dc.contributor.authorAytekin, Oezlem
dc.date.accessioned2024-08-04T20:58:58Z
dc.date.available2024-08-04T20:58:58Z
dc.date.issued2008
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe magnetic moments of Co+2 complexes in newly reported macrocyclic complexes containing amide, imine, and secondary amine functions are investigated by a semi-theoretical approach for various geometrical situations. It is found that in order to obtain the observed room temperature magnetic moments, some of the parameters, related to the geometry of the complexes, should be varied in the magnetic Hamiltonian. The calculations and experiments obtained from the literature suggest that the environments of complexes are low field distorted octahedral. It is also suggested that while the probability of orbital contribution to the magnetic moment is high, the probability of ferromagnetic interactions between two cobalt(II) ions in a dimeric unit is quite low.en_US
dc.identifier.endpage216en_US
dc.identifier.issn0193-4929
dc.identifier.issn2191-0227
dc.identifier.issue3en_US
dc.identifier.startpage203en_US
dc.identifier.urihttps://hdl.handle.net/11616/103304
dc.identifier.volume28en_US
dc.identifier.wosWOS:000261156800003en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherWalter De Gruyter Gmbhen_US
dc.relation.ispartofReviews in Inorganic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectmagnetizationen_US
dc.subjectmagnetic susceptibilityen_US
dc.subjectspin-orbit couplingen_US
dc.subjectcobalt(II) complexen_US
dc.subjectdistortionen_US
dc.subjectcovalancy factoren_US
dc.subjectorbital contribution, ferromagnetic exchangeen_US
dc.titleHIGH PROBABILITY OF LARGE ORBITAL ANGULAR MOMENTUM CONTRIBUTION TO THE MAGNETIC MOMENT OF COBALT(II) ION IN NEWLY REPORTED MACROCYCLIC COMPLEX CONTAINING AMIDE, IMINE AND SECONDARY AMINE FUNCTIONSen_US
dc.typeArticleen_US

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